Rivero is a married woman. She was first married to Ales Basseville 1995. They stayed together for three years and finally divorced in 1998. The reason for the divorce is not clear. She then started her affairs with her boyfriend, Jorge Mora. They finally got married on January 2001. Ines and Jorge welcomed their first child a daughter named Maia, on May 22, 2001. They still together and they are living in Miami Beach, Florida. She used to reside in New York City.
When she was 16, she was discovered by agent Rivero through her modeling school in her hometown, Cordoba. A year later, she had a major success in her career. She won the of the "Elite Look of the Year" contest in Argentina. Her huge success came when she signed with Victoria’s Secret to become one of their notable Angels. An Angel contract helps models gain fame within the industry. Later in 2012, she decided to experience the other side of the modeling industry and joined the cast of the new reality show ‘Model Latina South Beach and she compete there to win a prize that net worth was $25,000. She is also earning a huge salary through her modeling career.